Polyacrylamide conjugated with poly(oxyethylene)-block-poly(oxypropylene)-block-poly(oxyethylene): a self-assembling material

被引:16
作者
Bromberg, L [1 ]
机构
[1] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA
关键词
D O I
10.1002/marc.1998.030190906
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel one-step synthesis of hydrophobically modified polyacrylamide (PAAm) is described. Triblock copolymers of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PEO-PPO-PEO) are grafted onto PAAm in melts of acrylamide in the presence of benzoyl peroxide. The resulting PEO-PPO-PEO-g-PAAm graft copolymers are capable of self-assembly in response to temperature changes in aqueous media.
引用
收藏
页码:467 / 471
页数:5
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