Synthesis, structure, and electrochemistry of a dodecanuclear chromium cluster complex [Cr12S16(PEt(3))(10)]

被引：19

作者：

Kamiguchi, S ^{[1
]}

Imoto, H ^{[1
]}

Saito, T ^{[1
]}

机构：

[1] UNIV TOKYO, SCH SCI, DEPT CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 07期

关键词：

D O I：

10.1246/cl.1996.555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dodecanuclear chromium sulfide cluster complex [Cr12S16(PEt(3))(10)] has been synthesized by the reaction of a hexanuclear cluster complex [Cr6S8(PEt(3))(6)] with sulfur. This complex has two octahedral Cr6S8 cores that are linked by two Cr-S bonds. The intercluster bonding mode is similar to that in the Chevrel phases. Cyclic voltammetry shows the existence of the intercluster electronic interaction between the two Cr6S8 cluster units.

引用

页码：555 / 556

页数：2

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