Development of novel and efficient synthesis of group 14 element (Ge and Sn) catenates by use of samarium (II) diiodide

被引：25

作者：

Azemi, T ^{[1
]}

Yokoyama, Y ^{[1
]}

Mochida, K ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 06期

关键词：

group; 14; elements; catenates; samarium (II) diiodide;

D O I：

10.1016/j.jorganchem.2004.12.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Group 14 element catenates such as di-, tri-, poly-germanes, and polystannanes are efficiently synthesized by use of the one-electron reducing agent Sml(2) under mild homogeneous conditions in good yields. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1588 / 1593

页数：6

共 45 条

[1] SOME SYNTHESES AND REACTIONS OF GROUP 4B ORGANOMETALLIC COMPOUNDS CONTAINING NITROGEN OXYGEN SULPHUR AND SELENIUM [J].

ABEL, EW ;

ARMITAGE, DA ;

BRADY, DB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 5 (02) :130-&

[2] REACTIONS OF TRIETHYLGERMANIUM HYDRIDE WITH SALTS OF TRANSITIONAL ELEMENTS AND WITH ORGANIC HALOACIDS [J].

ANDERSON, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (02) :326-328

[3] ISOPROPYLGERMANIUM HALIDES, OXIDES AND HYDROXIDE - GRIGNARD REACTION [J].

ANDERSON, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (04) :814-816

[4] TRI-NORMAL-BUTYLGERMANIUM ESTERS, HALIDES, ISOCYANATE AND OXIDE [J].

ANDERSON, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (12) :5800-5802

[5]

BAUER H, 1934, CHEM BER, P2617

[6] TRIPHENYLGERMYLPALLADIUM COMPLEXES [J].

BROOKS, EH ;

GLOCKLIN.F .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (09) :1241-&

[7]

BULTEN EJ, 1966, TETRAHEDRON LETT, P4389

[8]

BULTEN EJ, 1966, TETRAHEDRON LETT, V36, P4389

[9] STUDIES IN GROUP 4 ORGANOMETALLIC CHEMISTRY .22. SYNTHESIS OF TIN-GERMANIUM COMPOUNDS BY HYDROGENOLYTIC FISSION OF METAL(4)-NITROGEN BONDS [J].

CREEMERS, HM ;

NOLTES, JG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 7 (02) :237-&

[10]

DAVIS DD, 1970, ORGANOMET CHEM REV A, V6, P283

← 1 2 3 4 5 →