Surface modification of zinc oxide nanoparticles by aminopropyltriethoxysilane

被引：121

作者：

Grasset, F

Saito, N

Li, D

Park, D

Sakaguchi, I

Ohashi, N

Haneda, H

Roisnel, T

Mornet, S

Duguet, E

机构：

[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan

[2] Univ Rennes 1, Inst Chim, UMR CNRS 6512, Lab Verres & Ceram, F-35042 Rennes, France

[3] Univ Rennes 1, Inst Chim, UMR CNRS 6511, Lab Chim Solide & Inorgan Mol, F-35042 Rennes, France

[4] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2003年 / 360卷 / 1-2期

关键词：

ceramics; nanostructured materials; oxide materials; surfaces; chemical synthesis;

D O I：

10.1016/S0925-8388(03)00371-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Commercial zinc oxide nanoparticles (20-30 nm) were coated by aminopropyltriethoxysilane (APTES) under varying environments. Three different processes, acidic, basic and toluene were used. The effects of coating conditions (acidic, basic and toluene) on the grafting, structural and optical properties of these nanoparticles were studied. In the three cases, it was possible to control the coating and according to X-ray diffraction, BET, TEM and SEM results, it is clear that the APTES coating plays a role of growth inhibitor even at 800 degreesC. From diffuse reflectance measurements, one can notice that the grafting process did not modify the transmittance spectra of ZnO. (C) 2003 Elsevier B.V. All rights reserved.

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页码：298 / 311

页数：14

相关论文

共 33 条

[1] The adsorption of alkoxysilanes on oxidised aluminium substrates [J].

Abel, ML ;

Watts, JF ;

Digby, PP .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1998, 18 (03) :179-192

[2] X-ray diffraction study of the early stages of the growth of nanoscale zinc oxide crystallites obtained from thermal decomposition of four precursors. General concepts on precursor-dependent microstructural properties [J].

Audebrand, N ;

Auffredic, JP ;

Louer, D .

CHEMISTRY OF MATERIALS, 1998, 10 (09) :2450-2461

[3] PREPARATION AND CHARACTERIZATION OF QUANTUM SIZE ZINC-OXIDE - A DETAILED SPECTROSCOPIC STUDY [J].

BAHNEMANN, DW ;

KORMANN, C ;

HOFFMANN, MR .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (14) :3789-3798

[4] Preparation of functional silane-stabilized gold colloids in the (sub)nanometer size range [J].

Buining, PA ;

Humbel, BM ;

Philipse, AP ;

Verkleij, AJ .

LANGMUIR, 1997, 13 (15) :3921-3926

[5] ZnO as a novel photonic material for the UV region [J].

Chen, YF ;

Bagnall, D ;

Yao, TF .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 75 (2-3) :190-198

[6] THE STRUCTURE OF GAMMA-AMINOPROPYLTRIETHOXYSILANE ON GLASS SURFACES [J].

CHIANG, CH ;

ISHIDA, H ;

KOENIG, JL .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 74 (02) :396-404

[7] Effect of pH and impurities on the surface charge of zinc oxide in aqueous solution [J].

Degen, A ;

Kosec, M .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (06) :667-673

[8] Electrochemical deposition of zinc oxide films from non-aqueous solution: a new buffer/window process for thin film solar cells [J].

Gal, D ;

Hodes, G ;

Lincot, D ;

Schock, HW .

THIN SOLID FILMS, 2000, 361 :79-83

[9] THE STRUCTURE OF AN AMINOSILANE COUPLING AGENT IN AQUEOUS-SOLUTIONS AND PARTIALLY CURED SOLIDS [J].

ISHIDA, H ;

NAVIROJ, S ;

TRIPATHY, SK ;

FITZGERALD, JJ ;

KOENIG, JL .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1982, 20 (04) :701-718

[10] Powder design for UV-attenuating agent with high transparency for visible light [J].

Iwasaki, T ;

Satoh, M ;

Masuda, T ;

Fujita, T .

JOURNAL OF MATERIALS SCIENCE, 2000, 35 (16) :4025-4029

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