A soluble and highly functional polyaniline-carbon nanotube composite

被引:95
作者
Sainz, R
Benito, AM
Martínez, MT
Galindo, JF
Sotres, J
Baró, AM
Corraze, B
Chauvet, O
Dalton, AB
Baughman, RH
Maser, WK
机构
[1] CSIC, Inst Carboquim, Zaragoza 50018, Spain
[2] Univ Autonoma Madrid, Dept Fis Mat Condensada, Lab Nuevas Microscopias, E-28049 Madrid, Spain
[3] Nanotec Electron SL, Madrid 28049, Spain
[4] LPC, Inst Mat Jean Rouxel, F-44322 Nantes, France
[5] Univ Texas, UTD Nanotech Inst, Richardson, TX 75083 USA
关键词
D O I
10.1088/0957-4484/16/5/003
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A completely soluble polyaniline-multi-wall carbon nanotube (CNT-PANI) composite with drastically enhanced conductivity, improved thermal stability, and luminescent behaviour, has been synthesized. The presence of straight multi-wall carbon nanotubes during the polymerization of aniline induces the formation of a more planar conformation of polyaniline which acts as coating layer for the carbon nanotubes and leads to favourable interaction between the constituents. The polyaniline-coated multi-wall carbon nanotubes align into bundles and form a three-dimensional network in the overall composite. A highly functional carbon nanotube composite completely soluble in n-methylpyrrolidinone (NMP) exhibiting all the favourable processing and transformation possibilities of PANI has been obtained. These findings have important consequences for practical technological applications, especially for the development of opto-electronic devices.
引用
收藏
页码:S150 / S154
页数:5
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