Infinite dilution activity coefficients in chemical, environmental and biochemical engineering

被引：86

作者：

Sandler, SI

机构：

[1] Ctr. for Molec. and Eng. Thermodyn., Department of Chemical Engineering, University of Delaware, Newark

来源：

FLUID PHASE EQUILIBRIA | 1996年 / 116卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0378-3812(95)02905-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Here we briefly review several methods by which infinite dilution activity coefficients can be obtained, and then consider how such data can be used. In particular, we examine the accuracy of predictions of vapor-liquid equilibria over the complete concentration range, and over a range of temperatures based on infinite dilution activity coefficient data at a single temperature. Next, we review the direct use of infinite dilution activity coefficients in estimating the environmental fate of chemicals released into the atmosphere. Finally, the thermodynamics of some systems of biochemical interest are considered.

引用

页码：343 / 353

页数：11

共 30 条

[1]

BARISAS BG, 1986, THERMODYNAMIC DATA B, pCH9

[2]

CABINI S, 1986, THERMODYNAMIC DATA B

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