Tremella-like molybdenum dioxide consisting of nanosheets as an anode material for lithium ion battery

被引:164
作者
Yang, L. C. [1 ]
Gao, Q. S. [1 ]
Zhang, Y. H. [1 ]
Tang, Y. [1 ]
Wu, Y. P. [1 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
molybdenum dioxide; nanosheets; tremella; anode material; lithium ion battery;
D O I
10.1016/j.elecom.2007.11.009
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Tremella-like structured MoO2 consisting of nanosheets was obtained via a Fe2O3-assisted hydrothermal reduction of MoO3 in ethylenediamine aqueous solution. The as-prepared product was characterized and tested with scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV) and capacity measurement as anode material for lithium ion batteries. This structured MoO2 shows very high reversible capacity (>600 mA h g(-1)), good rate capability and cycling performance, presenting potential application as anode material for lithium ion batteries with high rate capability and high capacity. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:118 / 122
页数:5
相关论文
共 21 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   LITHIUM INTERCALATION CELLS WITHOUT METALLIC LITHIUM - MOO2/LICOO2 AND WO2/LICOO2 [J].
AUBORN, JJ ;
BARBERIO, YL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (03) :638-641
[3]   Selective synthesis of metastable MoO2 nanocrystallites through a solution-phase approach [J].
Chen, XY ;
Zhang, ZJ ;
Li, XX ;
Shi, CW ;
Li, XL .
CHEMICAL PHYSICS LETTERS, 2006, 418 (1-3) :105-108
[4]   XPS study of as-prepared and reduced molybdenum oxides [J].
Choi, JG ;
Thompson, LT .
APPLIED SURFACE SCIENCE, 1996, 93 (02) :143-149
[5]   Ordered nanoporous polymer-carbon composites [J].
Choi, M ;
Ryoo, R .
NATURE MATERIALS, 2003, 2 (07) :473-476
[6]   STRUCTURE AND ELECTROCHEMISTRY OF LIXMOO2 [J].
DAHN, JR ;
MCKINNON, WR .
SOLID STATE IONICS, 1987, 23 (1-2) :1-7
[7]   Preparation and characterization of three-dimentionally ordered mesoporus titania microparticles as anode material for lithium ion battery [J].
Fu, L. J. ;
Zhang, T. ;
Cao, Q. ;
Zhang, H. P. ;
Wu, Y. P. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (08) :2140-2144
[8]   Synthesis and electrochemical performance of novel core/shell structured nanocomposites [J].
Fu, LJ ;
Liu, H ;
Zhang, HP ;
Li, C ;
Zhang, T ;
Wu, YP ;
Holze, R ;
Wu, HQ .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (01) :1-4
[9]   Suppression of PC decomposition at the surface of graphitic carbon by Cu coating [J].
Gao, J. ;
Fu, L. J. ;
Zhang, H. P. ;
Zhang, T. ;
Wu, Y. P. ;
Wu, H. Q. .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (11) :1726-1730
[10]   Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].
Hu, JT ;
Odom, TW ;
Lieber, CM .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445