Supramolecular chemistry at interfaces

被引:12
作者
Huisman, BH
van Veggel, FCJM
Reinhoudt, DN
机构
[1] Univ Twente, Lab Supramol Chem & Technol, NL-7500 AE Enschede, Netherlands
[2] Univ Twente, MESA Res Inst, NL-7500 AE Enschede, Netherlands
关键词
D O I
10.1351/pac199870101985
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-assembly process of monolayers has been exploited as a tool to order and orient molecules with particular functions on flat gold surfaces in two dimensions. These functional adsorbates were derivatized with sulfide moieties for the adsorption on gold. The studied adsorbates include resorcin[4]arenes, calix[4]arenes, and carceplexes. Monolayers of these adsorbates on gold were prepared and characterized by means of a combination of various surface analytical techniques, including infrared spectroscopy, wetting, ellipsometry, X-ray Photoelectron Spectroscopy (XPS), Secondary Ion Mass Spectrometry (SIMS), electrochemistry, and Atomic Force Microscopy (AFM). The monomolecular films were studied for potential applications like sensing and switching.
引用
收藏
页码:1985 / 1992
页数:8
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