Growth of single-crystal α-MnO2 nanorods on multi-walled carbon nanotubes

被引:37
作者
Chen, Yong
Liu, Chen Guang
Liu, Chang
Lu, Gao Qing
Cheng, Hui Ming
机构
[1] Chinese Acad Sci, Met Res Inst, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
[2] Univ Queensland, Australian Inst Bioengn & Nanotechnol, ARC Ctr Funct Nanomat, St Lucia, Qld 4067, Australia
[3] Hainan Univ, MOE, Key Lab Trop Biol Resources, Haikou 570228, Peoples R China
基金
中国国家自然科学基金;
关键词
chemical synthesis; electron microscopy; X-ray diffraction;
D O I
10.1016/j.materresbull.2006.12.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Single-crystal alpha-MnO2 nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H2SO4 aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that alpha-MnO2 single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MVWNTs/ MnO2 composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO2 composites was improved largely compared to that using pure MWNTs and alpha-MnO2 nanorod mechanically mixed with MWNTs. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1935 / 1941
页数:7
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