Supramolecular chirality at the air/water interface [Invited]

被引：11

作者：

Benichou, Emmanuel ^{[1
]}

Derouet, Arnaud ^{[1
]}

Russier-Antoine, Isabelle ^{[1
]}

Jonin, Christian ^{[1
]}

Lascoux, Noelle ^{[1
]}

Liu, Minghua ^{[2
]}

Brevet, Pierre-Francois ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Spectrometrie Ion & Mol Lab, UMR 5579, F-69622 Villeurbanne, France

[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

来源：

OPTICAL MATERIALS EXPRESS | 2011年 / 1卷 / 01期

关键词：

SURFACE 2ND-HARMONIC GENERATION; 2ND-ORDER OPTICAL-ACTIVITY; 2ND HARMONIC-GENERATION; MOLECULAR CHIRALITY; POLARIZED PROBES; FILMS; SPECTROSCOPY; MONOLAYERS; EXPRESSION;

D O I：

10.1364/OME.1.000017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Second Harmonic Generation (SHG) was used to study the nonlinear optical properties of a two-dimensional film formed by the achiral amphiphilic compound 5-(octadecyloxy)-2-(2-thiazolylazo) phenol (TARC18) at the air-water interface. The S-polarized SHG intensity was measured as a function of the incident fundamental wave polarization angle during the monolayer compression. The method was applied to follow the emergence of chirality during the film compression and at constant surface pressure. The formation of molecular aggregates revealing supramolecular chirality was then demonstrated. It was shown furthermore that the origin of chirality was dominated by the magnetic contributions. (C) 2011 Optical Society of America

引用

页码：17 / 26

页数：10

共 32 条

[21] PHENOMENOLOGICAL TREATMENT OF SURFACE 2ND-HARMONIC GENERATION [J].

MIZRAHI, V ;

SIPE, JE .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1988, 5 (03) :660-667

[22] Chiroptical effects in the second harmonic signal of collagens I and IV [J].

Pena, AM ;

Boulesteix, T ;

Dartigalongue, T ;

Schanne-Klein, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (29) :10314-10322

[23] CIRCULAR-DICHROISM SPECTROSCOPY AT INTERFACES - A SURFACE 2ND HARMONIC-GENERATION STUDY [J].

PETRALLIMALLOW, T ;

WONG, TM ;

BYERS, JD ;

YEE, HI ;

HICKS, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (07) :1383-1388

[24] Chiral expression from molecular assemblies at metal surfaces: insights from surface science techniques [J].

Raval, R. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (03) :707-721

[25] Off resonance second order optical activity of isotropic layers of chiral molecules: Observation of electric and magnetic contributions [J].

Schanne-Klein, MC ;

Hache, F ;

Roy, A ;

Flytzanis, C ;

Payrastre, C .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (22) :9436-9443

[26]

Shen Y.R., 1984, The Principles of Nonlinear Optics, DOI [10.1017/S0263034600001889, DOI 10.1017/S0263034600001889]

[27] SURFACE 2ND HARMONIC-GENERATION - A NEW TECHNIQUE FOR SURFACE STUDIES [J].

SHEN, YR .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :69-86

[28] Second-order nonlinear optical properties of chiral materials [J].

Sioncke, S ;

Verbiest, T ;

Persoons, A .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2003, 42 (5-6) :115-155

[29] LINEARLY POLARIZED PROBES OF SURFACE CHIRALITY [J].

VERBIEST, T ;

KAURANEN, M ;

MAKI, JJ ;

TEERENSTRA, MN ;

SCHOUTEN, AJ ;

NOLTE, RJM ;

PERSOONS, A .

JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (18) :8296-8298

[30] SPONTANEOUS CHIRAL-SYMMETRY BREAKING BY ACHIRAL MOLECULES IN A LANGMUIR-BLODGETT-FILM [J].

VISWANATHAN, R ;

ZASADZINSKI, JA ;

SCHWARTZ, DK .

NATURE, 1994, 368 (6470) :440-443

← 1 2 3 4 →