Unexpected results of enyne metathesis using a ruthenium complex containing an N-heterocyclic carbene ligand

被引：83

作者：

Kitamura, T ^{[1
]}

Sato, Y ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 14期

关键词：

D O I：

10.1039/b101453f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metathesis of enyne having 1,1-substituted alkene, carried out with the new generation of a ruthenium carbene complex containing an N-heterocyclic carbene ligand, gave five- and six-membered cyclic compounds in high yield.

引用

页码：1258 / 1259

页数：2

共 30 条

[1] Armstrong SK, 1998, J CHEM SOC PERK T 1, P371
[2] Rapid entry into mono-, bi-, and tricyclic β-lactam arrays via alkene metathesis
Barrett, AGM
Baugh, SPD
Braddock, DC
Flack, K
Gibson, VC
Giles, MR
Marshall, EL
Procopiou, PA
White, AJP
Williams, DJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (22) : 7893 - 7907
[3] Bentz D, 2000, SYNTHESIS-STUTTGART, P1766
[4] READILY ACCESSIBLE 12-I-5 OXIDANT FOR THE CONVERSION OF PRIMARY AND SECONDARY ALCOHOLS TO ALDEHYDES AND KETONES
DESS, DB
MARTIN, JC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (22) : 4155 - 4156
[5] Fürstner A, 2000, ANGEW CHEM INT EDIT, V39, P3012
[6] Novel rearrangements of enynes catalyzed by PtCl2
Fürstner, A
Szillat, H
Stelzer, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) : 6785 - 6786
[7] Fürstner A, 1998, TOP ORGANOMETAL CHEM, V1, P37
[8] Recent advances in olefin metathesis and its application in organic synthesis
Grubbs, RH
Chang, S
[J]. TETRAHEDRON, 1998, 54 (18) : 4413 - 4450
[9] RING-CLOSING METATHESIS AND RELATED PROCESSES IN ORGANIC-SYNTHESIS
GRUBBS, RH
MILLER, SJ
FU, GC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (11) : 446 - 452
[10] An enyne metathesis/(4+2)-dimerization route to (±)-differolide
Hoye, TR
Donaldson, SM
Vos, TJ
[J]. ORGANIC LETTERS, 1999, 1 (02) : 277 - 279

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