New cyclodextrin derivatives as chiral selectors in capillary electrophoresis

被引：15

作者：

Cucinotta, V

Giuffrida, A

Grasso, G

Maccarrone, G

Mazzaglia, A

Vecchio, G

机构：

[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

[2] CNR, ISSN, I-95125 Catania, Italy

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 2001年 / 370卷 / 04期

关键词：

D O I：

10.1007/s002160100816

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The separation of three pairs of enantiomeric herbicides has been successfully achieved by capillary electrophoresis at two different pH values in the presence of cyclodextrin derivatives previously synthesized in our laboratory. Two of these derivatives constitute a new class of receptor, the hemispherodextrins, in which a trehalose capping moiety is bonded to beta -cyclodextrin. Because of their peculiar structure hemispherodextrins have very promising characteristics and the low receptor concentration required to achieve separation deserves particular interest.

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页码：363 / 366

页数：4

相关论文

共 28 条

[1] COORDINATION PROPERTIES OF 6-DEOXY-6-[1-(2-AMINO) ETHYLAMINO]-BETA-CYCLODEXTRIN AND THE ABILITY OF ITS COPPER(II) COMPLEX TO RECOGNIZE AND SEPARATE AMINO-ACID ENANTIOMERIC PAIRS [J].

BONOMO, RP ;

CUCINOTTA, V ;

DALLESSANDRO, F ;

IMPELLIZZERI, G ;

MACCARRONE, G ;

RIZZARELLI, E .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1993, 15 (02) :167-180

[2] Molecular recognition of amino acids by copper(II) complexes of 6(A),6(X)-diamino-6(A),6(X)-dideoxy-beta-cyclodextrin (X=B,C,D) [J].

Bonomo, RP ;

Pedotti, S ;

Vecchio, G ;

Rizzarelli, E .

INORGANIC CHEMISTRY, 1996, 35 (23) :6873-6877

[3]

Bonomo RP, 1997, CHIRALITY, V9, P341, DOI 10.1002/(SICI)1520-636X(1997)9:4<341::AID-CHIR5>3.0.CO

[4]

2-G

[5] CONFORMATIONAL FEATURES AND COORDINATION PROPERTIES OF FUNCTIONALIZED CYCLODEXTRINS - FORMATION, STABILITY, AND STRUCTURE OF PROTON AND COPPER(II) COMPLEXES OF HISTAMINE-BEARING BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION [J].

BONOMO, RP ;

CUCINOTTA, V ;

DALESSANDRO, F ;

IMPELLIZZERI, G ;

MACCARRONE, G ;

VECCHIO, G ;

RIZZARELLI, E .

INORGANIC CHEMISTRY, 1991, 30 (13) :2708-2713

[6] ABOUT SOME ASPECTS OF THE USE OF CHARGED CYCLODEXTRINS FOR CAPILLARY ELECTROPHORESIS ENANTIOSEPARATION [J].

CHANKVETADZE, B ;

ENDRESZ, G ;

BLASCHKE, G .

ELECTROPHORESIS, 1994, 15 (06) :804-807

[7]

Chankvetadze B., 1997, CAPILLARY ELECTROPHO

[8] Functionalized beta-cyclodextrins: Thermodynamic studies and NMR titration of 6-diethylenetriamine derivative [J].

Cucinotta, V ;

DAlessandro, F ;

Impellizzeri, G ;

Maccarrone, G ;

Rizzarelli, E ;

Vecchio, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (09) :1785-1788

[9] From capped to three-dimensional cyclodextrins:: the first example of a new class of receptors by trehalose capping of a β-cyclodextrin [J].

Cucinotta, V ;

Grasso, G ;

Vecchio, G .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1998, 31 (01) :43-55

[10]

CUCINOTTA V, 1999, P 4 C NAZ CHIM SUPR, P108