Porous lanthanide-organic framework with zeolite-like topology

被引:198
作者
Maji, TK
Mostafa, G
Chang, HC
Kitagawa, S [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Jadavpur Univ, Dept Phys, Kolkata 700032, W Bengal, India
关键词
D O I
10.1039/b500971e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two novel isomorphous porous frameworks of Ln( III), {[Ln(2)(imidc)(2)(H2O) (3)](H2O)}(n), [Ln = Gd(III) (1) and Er(III) (2)] have been synthesized hydrothermally using multifunctional 4,5-imidazoledicarboxylic acid (imidc) as a connector; they have a zeolite-like network topology which can provide another form upon dehydration, and exhibit selective adsorption properties for H2O over N-2, CO2 and MeOH.
引用
收藏
页码:2436 / 2438
页数:3
相关论文
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