Raman characterization and tunable growth of double-wall carbon nanotubes

被引:22
作者
Ci, LJ [1 ]
Zhou, ZP [1 ]
Yan, XQ [1 ]
Liu, DF [1 ]
Yuan, HJ [1 ]
Song, L [1 ]
Wang, JX [1 ]
Gao, Y [1 ]
Zhou, JJ [1 ]
Zhou, WY [1 ]
Wang, G [1 ]
Xie, SS [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Ctr Condensed Matter Phys, Beijing 100080, Peoples R China
关键词
D O I
10.1021/jp026516h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Double-wall carbon nanotubes (DWCNTs) were synthesized by pyrolyzing C2H2 on the sulfur-promoted floating iron catalyst. Similar to that of SWCNTs, Raman spectra of DWCNTs display two "fingerprint" features of the radial breathing mode (RBM) at the lower frequency range and the splitting tangential mode (TM). However, RBM frequencies of DWCNTs take a wider range and display much richer peaks than those of SWCNTs. The possible match of the inner tubes and the outer tubes according to the RBM bands was assigned, and different chirality types were discussed according to the diameter and chirality dependence of resonant Raman vibration. By changing experimental conditions, we can tunably grow different DWCNTs with various diameter distributions.
引用
收藏
页码:8760 / 8764
页数:5
相关论文
共 26 条
[1]   Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes [J].
Bandow, S ;
Asaka, S ;
Saito, Y ;
Rao, AM ;
Grigorian, L ;
Richter, E ;
Eklund, PC .
PHYSICAL REVIEW LETTERS, 1998, 80 (17) :3779-3782
[2]   Raman scattering study of double-wall carbon nanotubes derived from the chains of fullerenes in single-wall carbon nanotubes [J].
Bandow, S ;
Takizawa, M ;
Hirahara, K ;
Yudasaka, M ;
Iijima, S .
CHEMICAL PHYSICS LETTERS, 2001, 337 (1-3) :48-54
[3]   Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons [J].
Cheng, HM ;
Li, F ;
Su, G ;
Pan, HY ;
He, LL ;
Sun, X ;
Dresselhaus, MS .
APPLIED PHYSICS LETTERS, 1998, 72 (25) :3282-3284
[4]   Double wall carbon nanotubes promoted by sulfur in a floating iron catalyst CVD system [J].
Ci, LJ ;
Rao, ZL ;
Zhou, ZP ;
Tang, DS ;
Yan, YQ ;
Liang, YX ;
Liu, DF ;
Yuan, HJ ;
Zhou, WY ;
Wang, G ;
Liu, W ;
Xie, SS .
CHEMICAL PHYSICS LETTERS, 2002, 359 (1-2) :63-67
[5]   Carbon nanofibers and single-walled carbon nanotubes prepared by the floating catalyst method [J].
Ci, LJ ;
Wei, JQ ;
Wei, BQ ;
Liang, J ;
Xu, CL ;
Wu, DH .
CARBON, 2001, 39 (03) :329-335
[6]   Controllable growth of single wall carbon nanotubes by pyrolizing acetylene on the floating iron catalysts [J].
Ci, LJ ;
Xie, SS ;
Tang, DS ;
Yan, XQ ;
Li, YB ;
Liu, ZQ ;
Zou, XP ;
Zhou, WY ;
Wang, G .
CHEMICAL PHYSICS LETTERS, 2001, 349 (3-4) :191-195
[7]   Raman spectroscopy on isolated single wall carbon nanotubes [J].
Dresselhaus, MS ;
Dresselhaus, G ;
Jorio, A ;
Souza, AG ;
Saito, R .
CARBON, 2002, 40 (12) :2043-2061
[8]   Phonons in carbon nanotubes [J].
Dresselhaus, MS ;
Eklund, PC .
ADVANCES IN PHYSICS, 2000, 49 (06) :705-814
[9]   Phonon softening in metallic nanotubes by a Peierls-like mechanism [J].
Dubay, O ;
Kresse, G ;
Kuzmany, H .
PHYSICAL REVIEW LETTERS, 2002, 88 (23) :4
[10]   van der Waals interaction in nanotube bundles:: Consequences on vibrational modes [J].
Henrard, L ;
Hernández, E ;
Bernier, P ;
Rubio, A .
PHYSICAL REVIEW B, 1999, 60 (12) :R8521-R8524