Dediazoniation reactions of arenediazonium ions under solvolytic conditions:: fluoride anion abstraction from trifluoroethanol and α-hydrogen atom abstraction from ethanol

被引：25

作者：

Canning, PSJ ^{[1
]}

McCrudden, K ^{[1
]}

Maskill, H ^{[1
]}

Sexton, B ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 18期

关键词：

D O I：

10.1039/a804686g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arenediazonium salts decompose thermally and photochemically in trifluoroethanol to yield trifluoroethyl ethers and (in part by fluoride abstraction from the solvent) fluoroarenes; the less reactive compounds in trifluoroethanol decompose readily in ethanol to give arenes in a radical reaction involving abstraction of the ct-hydrogen from the ethanol.

引用

页码：1971 / 1972

页数：2

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