Ethanol and water adsorption in methanol-derived ZIF-71

被引：100

作者：

Lively, Ryan P. ^{[1
]}

Dose, Michelle E. ^{[2
]}

Thompson, Joshua A. ^{[2
]}

McCool, Benjamin A. ^{[1
]}

Chance, Ronald R. ^{[1
,2
]}

Koros, William J. ^{[2
]}

机构：

[1] Algenol Biofuels, Bonita Springs, FL 34315 USA

[2] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 30期

关键词：

ALCOHOLS;

D O I：

10.1039/c1cc12728d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.

引用

收藏

页码：8667 / 8669

页数：3

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