Polyoxometalates nanoparticles: synthesis, characterization and carbon nanotube modification

被引：55

作者：

Kang, ZH ^{[1
]}

Wang, YB ^{[1
]}

Wang, EB ^{[1
]}

Lian, SY ^{[1
]}

Gao, L ^{[1
]}

You, WS ^{[1
]}

Hu, CW ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

SOLID STATE COMMUNICATIONS | 2004年 / 129卷 / 09期

关键词：

polyoxometalates nanoparticles; carbon nanotubes; chemical modification;

D O I：

10.1016/j.ssc.2003.12.012

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

In this paper, we described a large-scale synthesis method of the polyoxometalates (POMs) nanoparticles and the modification of carbon nanotube (CNTs) through a chemical modified approach. Four types of POMs nanoparticles were prepared by a one-step solid-state reaction at room temperature and characterized by IR, elemental analyses, XRD and TEM. These uniform nanoparticles have an average size of 8-10 nm. Furthermore, based on chemical adsorption between POMs and carboxylic acid groups, which were introduced to the CNTs by adding dilute nitric acid, POMs nanoparticles were successfully located on the CNTs as the modifier. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：559 / 564

页数：6

共 42 条

[1] DIRECT W-183 NUCLEAR MAGNETIC-RESONANCE - A POWERFUL NEW STRUCTURAL TOOL FOR HETEROPOLY-TUNGSTATES AND ISOPOLYTUNGSTATE CHEMISTRY
ACERETE, R
HAMMER, CF
BAKER, LCW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (01) : 267 - 269
[2] Nanotubes from carbon
Ajayan, PM
[J]. CHEMICAL REVIEWS, 1999, 99 (07) : 1787 - 1799
[3] Directly observed covalent coupling of quantum dots to single-wall carbon nanotubes
Azamian, BR
Coleman, KS
Davis, JJ
Hanson, N
Green, MLH
[J]. CHEMICAL COMMUNICATIONS, 2002, (04) : 366 - 367
[4] Crystal structure and replacement reaction of coordinated water molecules of the heteropoly compounds of sandwich-type tungstoarsenates
Bi, LH
Wang, EB
Peng, J
Huang, RD
Xu, L
Hu, CW
[J]. INORGANIC CHEMISTRY, 2000, 39 (04) : 671 - 679
[5] Mercury(II) immobilized on carbon nanotubes: Synthesis, characterization, and redox properties
Bond, AM
Miao, WJ
Raston, CL
[J]. LANGMUIR, 2000, 16 (14) : 6004 - 6012
[6] Reversible sidewall functionalization of buckytubes
Boul, PJ
Liu, J
Mickelson, ET
Huffman, CB
Ericson, LM
Chiang, IW
Smith, KA
Colbert, DT
Hauge, RH
Margrave, JL
Smalley, RE
[J]. CHEMICAL PHYSICS LETTERS, 1999, 310 (3-4) : 367 - 372
[7] Solution properties of single-walled carbon nanotubes
Chen, J
Hamon, MA
Hu, H
Chen, YS
Rao, AM
Eklund, PC
Haddon, RC
[J]. SCIENCE, 1998, 282 (5386) : 95 - 98
[8] Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
Chen, RJ
Zhang, YG
Wang, DW
Dai, HJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) : 3838 - 3839
[9] Spontaneous reduction of metal ions on the sidewalls of carbon nanotubes
Choi, HC
Shim, M
Bangsaruntip, S
Dai, HJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (31) : 9058 - 9059
[10] Polyoxometalate-based molecular materials
Coronado, E
Gomez-Garcia, CJ
[J]. CHEMICAL REVIEWS, 1998, 98 (01) : 273 - 296

← 1 2 3 4 5 →