Thermodynamic behavior of mixtures .3. Mixtures of acetonitrile with dimethylacetamide, dimethyl sulfoxide, nitrobenzene, and methanol at 25 degrees C

被引:76
作者
Bakshi, MS
Singh, J
Kaur, H
Ahmad, ST
Kaur, G
机构
[1] PANJAB UNIV, DEPT CHEM, CHANDIGARH 160014, INDIA
[2] JAMIA MILLIA ISLAMIA, FAC ENGN & TECHNOL,DEPT APPL SCI & HUMANITIES, NEW DELHI 110025, INDIA
[3] UNIV DELHI, DEPT ELECT SCI, NEW DELHI 110021, INDIA
关键词
D O I
10.1021/je960180l
中图分类号
O414.1 [热力学];
学科分类号
摘要
Ultrasonic velocities (u), densities (rho), viscosities (eta), relative permittivities (epsilon), and refractive indicies (n(D)) of mixtures of acetonitrile with dimethylacetamide, dimethyl sulfoxide, nitrobenzene, and methanol have been measured at 25 degrees C. From u, rho, and eta, isentropic compressibilities (kappa(B)), and its deviation from ideal behavior (kappa(s)(E)), and excess viscosities (Delta eta) have been computed. From n(D) and epsilon, the Kirkwood correlation factor, g, has also been evaluated.
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页码:1459 / 1461
页数:3
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