A new azaferrocenophane with an azobenzene-containing ligand. Remote control of photoisomerization of the azobenzene group by redox of the iron center

被引:29
作者
Horie, M [1 ]
Sakano, T [1 ]
Osakada, K [1 ]
Nakao, H [1 ]
机构
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
关键词
D O I
10.1021/om034163i
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Azobenzene-introduced azaferrocenophanes have been newly synthesized by coupling reactions catalyzed by transition-metal complexes. The photochemical response of the azobenzene group is controlled by the oxidation state of the molecule.
引用
收藏
页码:18 / 20
页数:3
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