Photochemistry as a green synthetic method

被引：8

作者：

Albini, Angelo ^{[1
]}

Fagnoni, Maurizio ^{[1
]}

机构：

[1] Univ Pavia, Dept Organ Chem, I-27100 Pavia, Italy

来源：

NEW METHODOLOGIES AND TECHNIQUES FOR A SUSTAINABLE ORGANIC CHEMISTRY | 2008年 / 246卷

关键词：

photochemistry; arylation;

D O I：

10.1007/978-1-4020-6793-8_13

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photon is the green reagent par excellence. It is absorbed leaving no residue and induces deep-seated chemical transformations under mild conditions. Reactions via electronic excited states often reach the target via a shorter path than thermal alternatives, with excellent atom economy. Photochemistry also offers a way for the mild generation of highly reactive intermediates such as radicals or ions. This is illustrated by the example of arylation reactions via photo S-N 1 process, a method that under some aspects rivals Pd-catalyzed reactions.

引用

页码：279 / 293

页数：15

共 32 条

[1] Green chemistry and photochemistry were born at the same time [J].