Asymmetric auto-inductive aldol reaction by self-assembly of chiral ligands

被引：17

作者：

De Rosa, M ^{[1
]}

Acocella, MR ^{[1
]}

Soriente, A ^{[1
]}

Scettri, A ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, Salerno, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(01)00261-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Ti(IV)/(R)-BINOL catalyzed aldol condensation of trimethylsilyloxydiene, deriving from 2,2,6-trimethyl-4H-[1,3]-dioxin-4-one, is shown to proceed through an auto-inductive process with amplification of enantiomeric excess (e.e.). (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：1529 / 1531

页数：3

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