Monte carlo study of the second virial coefficient of star polymers in a good solvent

被引:33
作者
Ohno, K [1 ]
Shida, K [1 ]
Kimura, M [1 ]
Kawazoe, Y [1 ]
机构
[1] JAPAN ADV INST SCI & TECHNOL,TATSUNOKUCHI,ISHIKAWA 92021,JAPAN
关键词
D O I
10.1021/ma950742q
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The self- and mutual-avoiding effects of two star polymers in a good solvent are studied by means of a simple Monte Carlo sampling technique on a cubic lattice, using an enrichment algorithm. The total number of configurations is determined as a function of the distance between the two star polymers. The radius of gyration of a single star polymer, the second virial coefficient, the effective interstar potential, and the penetration function are evaluated for 3- to 6-arm star polymers. Considerable deviation from the result of the previous naive first-order epsilon-expansion is observed in the penetration function. We also discuss the value of the penetration function in the infinite-arm limit, according to the cone picture.
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页码:2269 / 2274
页数:6
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