New egg-shaped fullerenes:: non-isolated pentagon structures of Tm3N@Cs(51365)-C84 and Gd3N@Cs(51365)-C84

被引：84

作者：

Zuo, Tianming ^{[3
]}

Walker, Kenneth ^{[4
]}

Olmstead, Marilyn M. ^{[1
]}

Melin, Frederic ^{[2
]}

Holloway, Brian C. ^{[4
]}

Echegoyen, Luis ^{[2
]}

Dorn, Harry C. ^{[3
]}

Chaur, Manuel N. ^{[2
]}

Chancellor, Christopher J. ^{[1
]}

Beavers, Christine M. ^{[1
]}

Balch, Alan L. ^{[1
]}

Athans, Andreas J. ^{[2
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[3] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

[4] Luna Innovat Inc, Nanoworks Div, Danville, VA 24541 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 09期

关键词：

D O I：

10.1039/b716037b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although there are 51 568 non-IPR and 24 IPR structures for C-84, the egg-shaped endohedral fullerenes Tm3N@Cs(51 365)C-84 and Gd3N@Cs(51 365)-C-84 utilize the same non-IPR cage structure as found initially for Tb3N@Cs(51 365)-C-84.

引用

页码：1067 / 1069

页数：3

共 23 条

[1] Tb3N@C84:: An improbable, egg-shaped endohedral fullerene that violates the isolated pentagon rule [J].

Beavers, Christine M. ;

Zuo, Tianming ;

Duchamp, James C. ;

Harich, Kim ;

Dorn, Harry C. ;

Olmstead, Marilyn M. ;

Balch, Alan L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (35) :11352-11353

[2] Structure and enhanced reactivity rates of the D5h Sc3N@C80 and Lu3N@ C80 metallofullerene isomers:: The importance of the pyracylene motif [J].

Cai, Ting ;

Xu, Liaosa ;

Anderson, Mark R. ;

Ge, Zhongxin ;

Zuo, Tianming ;

Wang, Xuelei ;

Olmstead, Marilyn M. ;

Balch, Alan L. ;

Gibson, Harry W. ;

Dorn, Harry C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) :8581-8589

[3] General rule for the stabilization of fullerene cages encapsulating trimetallic nitride templates [J].

Campanera, JM ;

Bo, C ;

Poblet, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (44) :7230-7233

[4] Gd3N@C2n (n=40, 42, and 44):: Remarkably low HOMO-LUMO gap and unusual electrochemical reversibility of Gd3N@C88 [J].

Chaur, Manuel N. ;

Melin, Frederic ;

Elliott, Bevan ;

Athans, Andreas J. ;

Walker, Kenneth ;

Holloway, Brian C. ;

Echegoyen, Luis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (47) :14826-14829

[5]

Fowler P.W., 2006, ATLAS FULLERENES

[6] Purification of endohedral trimetallic nitride fullerenes in a single, facile step [J].

Ge, ZX ;

Duchamp, JC ;

Cai, T ;

Gibson, HW ;

Dorn, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) :16292-16298

[7] Structure of a missing-caged metallofullerene:: La2 @ C72 [J].

Kato, H ;

Taninaka, A ;

Sugai, T ;

Shinohara, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) :7782-7783

[8] Endohedral metallofullerenes. Are the isolated pentagon rule and fullerene structures always satisfied? [J].

Kobayashi, K ;

Nagase, S ;

Yoshida, M ;

Osawa, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) :12693-12694

[9] Sc3N@C68:: Folded pentalene coordination in an endohedral fullerene that does not obey the isolated pentagon rule [J].

Olmstead, MM ;

Lee, HM ;

Duchamp, JC ;

Stevenson, S ;

Marciu, D ;

Dorn, HC ;

Balch, AL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (08) :900-+

[10] Comparative investigation on non-IPR C68 and IPR C78 fullerenes encaging Sc3N molecules [J].

Park, SS ;

Liu, D ;

Hagelberg, F .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (39) :8865-8873

← 1 2 3 →