New silica-gel-bound polyazacycloalkanes and characterization of their copper(II) complexes using electron spin resonance spectroscopy

被引：32

作者：

Gros, C

Rabiet, F

Denat, F

Brandes, S

Chollet, H

Guilard, R

机构：

[1] UNIV BOURGOGNE,FAC SCI GABRIEL,UMR 9953,LAB INGN MOL SEPARAT & APPLICAT GAZ,F-21000 DIJON,FRANCE

[2] CEA,CTR ETUD VALDUC,F-21120 IS SUR TILLE,FRANCE

[3] UNIV BOURGOGNE,FAC SCI GABRIEL,URA 1685,LAB SYNTH & ELECTROSYNTH ORGANOMET,F-21100 DIJON,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 07期

关键词：

D O I：

10.1039/dt9960001209

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several tetraazamacrocycle-bonded silica gels have been synthesized and characterized. 1,4,7,10-Tetraazacyclbdodecane, 1,4,8,11-tetraazacyclotetradecane and 1,5,9,13-tetraazacyclohexadecane have been covalently bound to silica gel and their respective copper(II) complexes characterized. Three different methods were used for capacity determinations: quantitative ESR measurements of copper(II) complexes, nitrogen, carbon and copper elemental analysis and UV/VIS measurements.

引用

页码：1209 / 1214

页数：6

共 27 条

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