Construction of a homooxacalix[3]arene-based dimeric capsule cross-linked by a Pd(II)-pyridine interaction

被引：39

作者：

Ikeda, A

Yoshimura, M

Tani, F

Naruta, Y

Shinkai, S

机构：

[1] Kyushu Univ, Fac Engn, Dept Chem Sci & Technol, Fukuoka 812, Japan

[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 812, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 07期

关键词：

D O I：

10.1246/cl.1998.587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homooxacalix[3]arenes bearing 4-pyridyl groups at the 7,15,23-positions formed a dimeric complex with Pd(II). Only when the homooxacalix[3]arene was preorganized to a cone conformation, a dimeric molecular capsule with D-3h symmetry was yielded. Mass spectral studies established that CD2Cl2 is included in this cavity.

引用

收藏

页码：587 / 588

页数：2

相关论文

共 13 条

[1] Chiral recognition of alpha-amino acid derivatives with a homooxacalix[3]arene: Construction of a pseudo-C-2-symmetrical compound from a C-3-symmetrical macrocycle [J].

Araki, K ;

Inada, K ;

Shinkai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01) :72-74

[2] CONFORMATIONAL ISOMERISM IN AND BINDING-PROPERTIES TO ALKALI-METALS AND AN AMMONIUM SALT OF O-ALKYLATED HOMOOXACALIX[3]ARENES [J].

ARAKI, K ;

INADA, K ;

OTSUKA, H ;

SHINKAI, S .

TETRAHEDRON, 1993, 49 (42) :9465-9478

[3] CALIXARENE-BASED MOLECULAR CAPSULE [J].

ARIMURA, T ;

MATSUMOTO, S ;

TESHIMA, O ;

NAGASAKI, T ;

SHINKAI, S .

TETRAHEDRON LETTERS, 1991, 32 (38) :5111-5114

[4] PREPARATION OF A MACROCYCLIC POLYNUCLEAR COMPLEX, [(EN)PD(4,4'-BPY)]4(NO3)8, WHICH RECOGNIZES AN ORGANIC-MOLECULE IN AQUEOUS-MEDIA [J].

FUJITA, M ;

YAZAKI, J ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5645-5647

[5]

Gutsche C.D., 1989, CALIXARENE

[6] On the prerequisites for the formation of solution complexes from [60]fullerene and calix[n]arenes: a novel allosteric effect between [60]fullerene and metal cations in calix[n]aryl ester complexes [J].

Ikeda, A ;

Suzuki, Y ;

Yoshimura, M ;

Shinkai, S .

TETRAHEDRON, 1998, 54 (11) :2497-2508

[7] Metal-induced self-assembly of cavitand-based cage molecules [J].

Jacopozzi, P ;

Dalcanale, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :613-615

[8] SELF-ASSEMBLED MOLECULAR CAPSULE BASED ON THE HYDROGEN-BONDING INTERACTION BETWEEN 2 DIFFERENT CALIX[4]ARENES [J].

KOH, K ;

ARAKI, K ;

SHINKAI, S .

TETRAHEDRON LETTERS, 1994, 35 (44) :8255-8258

[9] Synthesis and assembly of self-complementary calix[4]arenes [J].

Shimizu, KD ;

Rebek, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1995, 92 (26) :12403-12407

[10] TRANSITION-METAL BASED CATIONIC MOLECULAR BOXES - SELF-ASSEMBLY OF MACROCYCLIC PLATINUM(II) AND PALLADIUM(II) TETRANUCLEAR COMPLEXES [J].

STANG, PJ ;

CAO, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (11) :4981-4982