Base-catalyzed amination of olefins: an example of an environmentally friendly synthesis of amines

被引：18

作者：

Beller, M ^{[1
]}

Breindl, C ^{[1
]}

机构：

[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

CHEMOSPHERE | 2001年 / 43卷 / 01期

关键词：

amination; base catalysts; N-arylethylamines; catalysis;

D O I：

10.1016/S0045-6535(00)00319-2

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The base-catalyzed amination of aromatic olefins is described as an environmentally friendly synthesis of various beta -arylethylamines. Primary and secondary aliphatic amines as well as aromatic amines react with styrene derivatives to give the corresponding beta -arylethylamines in high yield up to 99%. While aliphatic amines react with styrenes in the presence of n-BuLi as the pre-catalyst, anilines can be olefinated using KOtBu as the catalyst. (C) 2001 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：21 / 26

页数：6

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