Self-assembly of luminescent molecular squares featuring octahedral rhenium corners

被引：219

作者：

Slone, RV ^{[1
]}

Hupp, JT ^{[1
]}

Stern, CL ^{[1
]}

AlbrechtSchmitt, TE ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 14期

关键词：

D O I：

10.1021/ic960464r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new family of molecular squares containing Re-I polypyridyl and polypyrazyl centers has been synthesized at quantitative yields via a self-assembly method. Ambient-temperature photophysical studies reveal that two of the squares (4,4'-bipyridine- and pyrazine-bridged species) readily luminesce in solution from relatively long-lived charge-transfer excited states. These squares expand the growing field of inorganic cyclophane self-assembly chemistry to the octahedral metal systems.

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页码：4096 / &

页数：3

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