Shift in low-frequency vibrational spectra of transition-metal zirconium compounds

被引:23
作者
Han, JG [1 ]
Wan, F
Zhu, ZY
Liao, Y
Ji, T
Ge, M
Zhang, ZY
机构
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
关键词
D O I
10.1063/1.2119419
中图分类号
O59 [应用物理学];
学科分类号
摘要
The far-infrared terahertz(THz) spectra of ZrC, ZrN, ZrO2, and ZrF4 have been measured using terahertz time-domain spectroscopy. The characterization of the frequency-dependent power absorption, index of refraction and complex dielectric function in the frequency range 0.1-2.0 THz are obtained. A standard Drude-Lorentz model gives a good fit on the transmission measurement results. We first observe the shift in the low-frequency vibrational spectra of different zirconium compounds. We analyze that the influence of the anion on the vibration modes causes the shift in low-frequency vibrational spectra of zirconic compounds. (C) 2005 American Institute of Physics.
引用
收藏
页码:1 / 3
页数:3
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