Purification and characterization of single-wall carbon nanotubes (SWNTs) obtained from the gas-phase decomposition of CO (HiPco process)

被引：669

作者：

Chiang, IW ^{[1
]}

Brinson, BE ^{[1
]}

Huang, AY ^{[1
]}

Willis, PA ^{[1
]}

Bronikowski, MJ ^{[1
]}

Margrave, JL ^{[1
]}

Smalley, RE ^{[1
]}

Hauge, RH ^{[1
]}

机构：

[1] Rice Univ, Dept Chem, Rice Quantum Inst, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 35期

关键词：

D O I：

10.1021/jp0114891

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A purification method is given for extracting the Fe metal catalyst and non-SWNT carbon from nanotubes produced by the HiPco process. (1,2) A multistage purification method has been investigated. Sample purity is documented by ESEM, TEM, TGA, Raman and UV-vis-near-IR spectroscopy. Metal catalyzed oxidation at low temperature has been shown to selectively remove non-SWNT carbon and permit extraction of iron with concentrated HCL Prolonged catalyzed oxidation has been found to preferentially remove smaller diameter tubes. The onset of oxidation of purified smaller diameter HiPco SWNTs is also found to be approximately 100 degreesC lower than for purified larger diameter tubes produced in the laser-oven process.

引用

页码：8297 / 8301

页数：5

共 14 条

[1] Purification and magnetic properties of carbon nanotubes
Bandow, S
Asaka, S
Zhao, X
Ando, Y
[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1998, 67 (01): : 23 - 27
[2] Reversible sidewall functionalization of buckytubes
Boul, PJ
Liu, J
Mickelson, ET
Huffman, CB
Ericson, LM
Chiang, IW
Smith, KA
Colbert, DT
Hauge, RH
Margrave, JL
Smalley, RE
[J]. CHEMICAL PHYSICS LETTERS, 1999, 310 (3-4) : 367 - 372
[3] Gas-phase production of carbon single-walled nanotubes from carbon monoxide via the HiPco process: A parametric study
Bronikowski, MJ
Willis, PA
Colbert, DT
Smith, KA
Smalley, RE
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2001, 19 (04): : 1800 - 1805
[4] Purification and characterization of single-wall carbon nanotubes
Chiang, IW
Brinson, BE
Smalley, RE
Margrave, JL
Hauge, RH
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06) : 1157 - 1161
[5] Dillon AC, 1999, ADV MATER, V11, P1354, DOI 10.1002/(SICI)1521-4095(199911)11:16<1354::AID-ADMA1354>3.0.CO
[6] 2-N
[7] Dujardin E, 1998, ADV MATER, V10, P611, DOI 10.1002/(SICI)1521-4095(199805)10:8<611::AID-ADMA611>3.0.CO
[8] 2-8
[9] HIDEFUMI H, 1995, MOL CRYST LIQ CRYS A, V276, P267
[10] OPENING AND PURIFICATION OF CARBON NANOTUBES IN HIGH YIELDS
HIURA, H
EBBESEN, TW
TANIGAKI, K
[J]. ADVANCED MATERIALS, 1995, 7 (03) : 275 - 276

← 1 2 →