Crystal engineering of Cu-containing metal-organic coordination polymers under hydrothermal conditions

被引:447
作者
Lu, JY [1 ]
机构
[1] Univ Houston Clear Lake, Dept Chem, Houston, TX 77058 USA
基金
美国国家航空航天局; 美国国家科学基金会;
关键词
crystal engineering; inclusion compounds; mixed valent copper iodine-containing coordination polymers; hydrothermal synthesis; oxidation and reduction reactions; chemical rearrangement reactions;
D O I
10.1016/j.cct.2003.08.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This account reviews Cu-containing polymeric coordination compounds synthesized under hydrothermal conditions. The rapid growth of hydrothermal synthesis of new coordination polymers is largely accredited to the developments in crystal engineering via functional network design. Both projected and unexpected framework structures have been obtained through oxidation, reduction, substitution, chemical rearrangement and regular hydrothermal reactions. New methods and reaction pathways play crucial roles in the formation of novel structures and topology under hydrothermal conditions. This review covers copper iodine-containing metal-organic coordination polymers, copper pyridylcarboxylate-containing metal-organic coordination polymers, and metastable coordination polymers with active copper open metal (OM) sites. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:327 / 347
页数:21
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