Poly(4′-vinylhexaphenylbenzene)s:: New carbon-rich polymers

被引：26

作者：

Kubel, C ^{[1
]}

Chen, SL ^{[1
]}

Mullen, K ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

MACROMOLECULES | 1998年 / 31卷 / 18期

关键词：

D O I：

10.1021/ma971707h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(4'-vinylhexaphenylbenzene) is a new, readily soluble polymer with hexaphenylbenzene side groups. The hexaphenylbenzene moieties can be cyclodehydrogenated oxidatively with CuCl2/AlCl3 yielding hexa-peri-hexabenzocoronene units and resulting in linked polycyclic aromatic hydrocarbons (PAHs). The synthesis of copolymers with methyl methacrylate (MMA) or styrene is also possible. Cyclodehydrogenation of the MMA copolymer leads to a partially soluble material, which can be characterized by UV/vis spectroscopy.

引用

页码：6014 / 6021

页数：8

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