Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas

被引:119
作者
Dhepe, PL
Ohashi, M
Inagaki, S
Ichikawa, M
Fukuoka, A [1 ]
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
[2] Japan Sci & Technol Agcy, CREST, Tokyo, Japan
[3] Toyota Cent Res & Dev Labs Inc, Aichi 4801192, Japan
基金
日本科学技术振兴机构;
关键词
sulfonated mesoporous silica; solid acid catalyst; sucrose; starch; hydrolysis;
D O I
10.1007/s10562-005-5850-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous silicas are modified with sulfonic acid groups either by one-pot or by grafting method. In the hydrolysis of sucrose and starch, the sulfonated mesoporous silicas work as water-tolerant recyclable solid acid catalysts, showing higher conversion and turnover frequency than conventional Amberlyst-15, Nafion-silica and HZSM-5 catalysts.
引用
收藏
页码:163 / 169
页数:7
相关论文
共 16 条
  • [1] Single-step preparation and catalytic activity of mesoporous MCM-41 and SBA-15 silicas functionalized with perfluoroalkylsulfonic acid groups analogous to Nafion®
    Alvaro, M
    Corma, A
    Das, D
    Fornés, V
    García, H
    [J]. CHEMICAL COMMUNICATIONS, 2004, (08) : 956 - 957
  • [2] Sulfonic acid functionalized mesoporous MCM-41 silica as a convenient catalyst for Bisphenol-A synthesis
    Das, D
    Lee, JF
    Cheng, SF
    [J]. CHEMICAL COMMUNICATIONS, 2001, (21) : 2178 - 2179
  • [3] Combined alkyl and sulfonic acid functionalization of MCM-41-type silica -: Part 1.: Synthesis and characterization
    Díaz, I
    Márquez-Alvarez, C
    Mohino, F
    Pérez-Pariente, J
    Sastre, E
    [J]. JOURNAL OF CATALYSIS, 2000, 193 (02) : 283 - 294
  • [4] Combined alkyl and sulfonic acid functionalization of MCM-41-Type silica -: Part 2.: Esterification of glycerol with fatty acids
    Díaz, I
    Márquez-Alvarez, C
    Mohino, F
    Pérez-Pariente, J
    Sastre, E
    [J]. JOURNAL OF CATALYSIS, 2000, 193 (02) : 295 - 302
  • [5] An ordered mesoporous organosilica hybrid material with a crystal-like wall structure
    Inagaki, S
    Guan, S
    Ohsuna, T
    Terasaki, O
    [J]. NATURE, 2002, 416 (6878) : 304 - 307
  • [6] SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE
    INAGAKI, S
    FUKUSHIMA, Y
    KURODA, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) : 680 - 682
  • [7] Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks
    Inagaki, S
    Guan, S
    Fukushima, Y
    Ohsuna, T
    Terasaki, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) : 9611 - 9614
  • [8] Direct syntheses of ordered SBA-15 mesoporous silica containing sulfonic acid groups
    Margolese, D
    Melero, JA
    Christiansen, SC
    Chmelka, BF
    Stucky, GD
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (08) : 2448 - 2459
  • [9] Water-tolerant solid acid catalysts
    Okuhara, T
    [J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3641 - 3665
  • [10] Reilly PJ, 1999, STARCH-STARKE, V51, P269, DOI 10.1002/(SICI)1521-379X(199909)51:8/9<269::AID-STAR269>3.0.CO