ZnO/Cr2O3 catalyst for reverse-water-gas-shift reaction of CAMERE process

被引：33

作者：

Park, SW ^{[1
]}

Joo, OS ^{[1
]}

Jung, KD ^{[1
]}

Kim, H ^{[1
]}

Han, SH ^{[1
]}

机构：

[1] Korea Inst Sci & Technol, Catalysis Lab, Seoul 130650, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2000年 / 17卷 / 06期

关键词：

CAMERE process; reverse-water-gas-shift reaction; Fe2O3/Cr2O3; ZnO/Cr2O3;

D O I：

10.1007/BF02699123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stability and the activity of Fe2O3/Cr2O3 and ZnO/Cr2O3 catalysts were examined for a reverse-water-gas-shift reaction (RWReaction). The initial activities of those catalysts were quite high so that the conversion reached close to equilibrium. The activity of Fe2O3/Cr2O3 catalyst decreased from 33.5 to 29.8% during the RWReaction for 75 h at 873 K with GHSV (ml/g(cat) . h) of 100,000. Moreover, the coke formation on the Fe2O3/Cr2O3 catalyst caused clogging in the RWReactor of the CAMERE process. On the other hand, the ZnO/Cr2O3 catalyst showed no coke formation and no deactivation for the RWReaction at 873 K with GHSV (ml/g(cat) . h) of 150,000. The ZnO/Cr2O3 was a good catalyst for the RWReaction of the CAMERE process.

引用

页码：719 / 722

页数：4

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