Preparation and examination of activated carbons from date pits impregnated with potassium hydroxide for the removal of methylene blue from aqueous solutions

被引:49
作者
Banat, F [1 ]
Al-Asheh, S [1 ]
Makhadmeh, L [1 ]
机构
[1] Jordan Univ Sci & Technol, Irbid 22110, Jordan
关键词
D O I
10.1260/026361703771953613
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The effect of chemical activation on the adsorption capacity of raw date pits towards the basic dye Methylene Blue (MB) was investigated. The raw material was impregnated with 30 wt% KOH solution followed by carbonization at 600degreesC for 2 h and activation with CO2 at 800degreesC for 1 h. The adsorption capacity increased from 80.3 mg/g to 123.1 mg/g upon chemical activation. Three simplified models including the pseudo-first-order, pseudo-second-order and intraparticle diffusion models were used to test the adsorption kinetics. The rates of adsorption were found to conform to pseudo-second-order kinetics with high correlation. The equilibrium results for MB adsorption on the activated carbon obtained from date pits were well fitted by the Langmuir isotherm equation.
引用
收藏
页码:597 / 606
页数:10
相关论文
共 23 条
[1]   Adsorption properties of activated carbons prepared from olive stones by chemical and physical activation [J].
Alaya, MN ;
Hourieh, MA ;
Youssef, AM ;
El-Sejariah, F .
ADSORPTION SCIENCE & TECHNOLOGY, 2000, 18 (01) :27-42
[2]  
BANAT F, 2003, IN PRESS PROCESS BIO
[3]  
GIRGIS B, 2002, MICROPOR MESOPOR MAT, V52, P5
[4]   Preparation of activated carbons from oil-palm-stone chars by microwave-induced carbon dioxide activation [J].
Guo, J ;
Lua, AC .
CARBON, 2000, 38 (14) :1985-1993
[5]   Effect of surface chemistry on gas-phase adsorption by activated carbon prepared from oil-palm stone with pre-impregnation [J].
Guo, J ;
Lua, AC .
SEPARATION AND PURIFICATION TECHNOLOGY, 2000, 18 (01) :47-55
[6]   Textural and chemical characterisations of activated carbon prepared from oil-palm stone with H2SO4 and KOH impregnation [J].
Guo, J ;
Lua, AC .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 32 (1-2) :111-117
[7]   Preliminary analysis and potential uses of date pits in foods [J].
Hamada, JS ;
Hashim, IB ;
Sharif, FA .
FOOD CHEMISTRY, 2002, 76 (02) :135-137
[8]  
Ho YS, 1998, CHEM ENG J, V70, P115, DOI 10.1016/S0923-0467(98)00076-1
[9]   Sorption studies of acid dye by mixed sorbents [J].
Ho, YS ;
Chiang, CC .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2001, 7 (02) :139-147
[10]  
Johns MM, 1998, J CHEM TECHNOL BIOT, V71, P131, DOI [10.1002/(SICI)1097-4660(199802)71:2<131::AID-JCTB821>3.0.CO