Low-temperature methanol synthesis from carbon dioxide and hydrogen via formic ester

被引：67

作者：

Fan, L ^{[1
]}

Sakaiya, Y ^{[1
]}

Fujimoto, K ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 1999年 / 180卷 / 1-2期

关键词：

carbon dioxide; hydrogenation; hydrogenolysis; methanol; ethyl formate;

D O I：

10.1016/S0926-860X(98)00345-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new route of methanol synthesis, at 443 K and under pressurized conditions, from carbon dioxide and hydrogen through formic ester was investigated, by using Cu-based catalysts. This one-pot reaction consisted of three steps: 1. formic acid synthesis from CO2 and H-2, 2. esterification of formic acid by ethanol to ethyl formate, and 3. hydrogenolysis of ethyl formate to methanol and ethanol. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：L11 / L13

页数：3

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