Polymerization of ethylene with metallocene/methylaluminoxane catalysts supported on polysiloxane micro gels and silica

被引：37

作者：

Alt, HG ^{[1
]}

Schertl, P ^{[1
]}

Koppl, A ^{[1
]}

机构：

[1] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 568卷 / 1-2期

关键词：

metallocene catalysts; micro gels; silica; support; ethylene polymerization;

D O I：

10.1016/S0022-328X(98)00841-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two kinds of fluorenyl containing zirconocene catalysts, supported on polymethyisiloxane micro gels and on silica, were prepared and applied for ethylene polymerizations using methylaluminoxane as cocatalyst. The observed activities were comparable with those of the corresponding silica supported catalysts. The average molecular weights of the obtained polymers differ from those of the corresponding homogeneous catalysts as from those of the silica supported systems. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：263 / 269

页数：7

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