Morphology change of calcium carbonate in the presence of polynucleotides

被引：21

作者：

Lukeman, Philip S. ^{[1
]}

Stevenson, Mary L. ^{[1
]}

Seeman, Nadrian C. ^{[1
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 04期

关键词：

D O I：

10.1021/cg700656r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-dimensional DNA lattices are grown under conditions that also are suitable for the magnesium-free growth of three-dimensional calcium carbonate crystals. These lattices are used to template morphology changes in calcium carbonate. The effects of DNA lattices, subassemblies, duplexes, single strands, dinucleotides, and mononucleotides on calcium carbonate morphology are studied. A polycrystalline morphology of calcite is found to predominate when a critical concentration of any polynucleotide is reached in the templating solution.

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页码：1200 / 1202

页数：3

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共 21 条

[1] Control of macromolecule distribution within synthetic and biogenic single calcite crystals [J].

Aizenberg, J ;

Hanson, J ;

Koetzle, TF ;

Weiner, S ;

Addadi, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (05) :881-886

[2] Calcium carbonate crystallization in the presence of biopolymers [J].

Butler, MF ;

Glaser, N ;

Weaver, AC ;

Kirkland, M ;

Heppenstall-Butler, M .

CRYSTAL GROWTH & DESIGN, 2006, 6 (03) :781-794

[3] GENE SYNTHESIS MACHINES - DNA CHEMISTRY AND ITS USES [J].

CARUTHERS, MH .

SCIENCE, 1985, 230 (4723) :281-285

[4] Directed nucleation of calcite at a crystal-imprinted polymer surface [J].

D'Souza, SM ;

Alexander, C ;

Carr, SW ;

Waller, AM ;

Whitcombe, MJ ;

Vulfson, EN .

NATURE, 1999, 398 (6725) :312-316

[5] The role of Mg2+ as an impurity in calcite growth [J].

Davis, KJ ;

Dove, PM ;

De Yoreo, JJ .

SCIENCE, 2000, 290 (5494) :1134-1137

[6]

Davis KJ, 2004, AM MINERAL, V89, P714

[7] A SYNTHETIC DNA MOLECULE IN 3 KNOTTED TOPOLOGIES [J].

DU, SM ;

STOLLAR, BD ;

SEEMAN, NC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (04) :1194-1200

[8] DNA DOUBLE-CROSSOVER MOLECULES [J].

FU, TJ ;

SEEMAN, NC .

BIOCHEMISTRY, 1993, 32 (13) :3211-3220

[9] Synthesis of needle-like aragonite from calcium chloride and sparingly soluble magnesium carbonate [J].

Hu, ZS ;

Deng, YL .

POWDER TECHNOLOGY, 2004, 140 (1-2) :10-16

[10] Effects of macromolecules on the crystallization of CaCO3 the formation of organic/inorganic composites [J].

Kato, T ;

Suzuki, T ;

Amamiya, T ;

Irie, T ;

Komiyama, N .

SUPRAMOLECULAR SCIENCE, 1998, 5 (3-4) :411-415