NOx reduction by potassium-containing coal briquettes.: Effect of NO2 concentration

被引：23

作者：

García-García, A ^{[1
]}

Illán-Gómez, MJ ^{[1
]}

Linares-Solano, A ^{[1
]}

de Lecea, CSM ^{[1
]}

机构：

[1] Univ Alicante, Dept Quim Inorgan, E-03080 Alicante, Spain

来源：

ENERGY & FUELS | 1999年 / 13卷 / 02期

关键词：

D O I：

10.1021/ef980165h

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The reactions of a potassium-containing bituminous coal briquette and the corresponding catalyst-free char with different NO/O-2 mixtures have been investigated at temperatures between 300 and 325 degrees C. The isothermal reactions have been followed by two techniques: thermogravimetry and gas chromatography + chemiluminescence analysis. A NO/NO2 mixture rich in NO2 results in a high carbon loss compared to that corresponding to the mixture poor in NO2. Despite that, NOx conversion is similar for both mixtures. The extra weight loss in the presence of a high concentration of NO2 is a consequence of NO2 reduction by carbon, producing NO and CO2 evolution.

引用

页码：499 / 505

页数：7

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