Spontaneous aggregation of octaalkoxyphthalocyanine metal complexes at an air-water interface

被引：28

作者：

Matsuzawa, Y ^{[1
]}

Seki, T ^{[1
]}

Ichimura, K ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

THIN SOLID FILMS | 1997年 / 301卷 / 1-2期

关键词：

aggregation; phthalocyanines;

D O I：

10.1016/S0040-6090(97)00006-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

1,4,8,11,15,18,22,25-Octaalkoxyphthalocy metal complexes were synthesized and spread on a pure water surface to reveal the properties of monolayer films using pi-A isotherm measurements, UV-visible absorption spectroscopy and Brewster angle microscopy. The results indicated that self-aggregation of the macrocycles occurs in monolayers spontaneously, even when no compression is applied. The mode of self-aggregation was influenced substantially by the alkoxy chain length and central metal ions.

引用

页码：162 / 168

页数：7

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