Optical properties of silver-dispersed PVP thin film

被引：107

作者：

Zheng, MP ^{[1
]}

Gu, MY ^{[1
]}

Jin, YP ^{[1
]}

Jin, GL ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, State Key Lab MMCS, Shanghai 200030, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 2001年 / 36卷 / 5-6期

关键词：

thin films; atomic force microscopy; optical properties;

D O I：

10.1016/S0025-5408(01)00525-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Silver-dispersed PVP (AS/PVP) thin films were prepared by spin coating from an alcohol solution of polyvinylprrolidone (PVP) in which silver nitrate were dissolved. A peak formed at 430-450 nm in the UV/VIS-spectra resulted from the surface plasma resonance of the silver nanoparticles. With the increase of annealing temperature, the plasma resonance absorption peak was broadened and intensities increased. The peak position of the surface plasma resonance also shifted to a high wavelength. XRD results confirmed the presence of silver particles in thin films. The absorption peak position calculated from the absorption spectrum is in very good agreement with Maxwell-Garnet (MG) theory using the dielectric constant of silver particles to calculate results of the absorption coefficient, cr, of the silver particles. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：853 / 859

页数：7

共 13 条

[1] Preparation and characterization of polymer thin films containing silver and silver sulfide nanoparticles [J].

Akamatsu, K ;

Takei, S ;

Mizuhata, M ;

Kajinami, A ;

Deki, S ;

Takeoka, S ;

Fujii, M ;

Hayashi, S ;

Yamamoto, K .

THIN SOLID FILMS, 2000, 359 (01) :55-60

[2] In-situ formation of Ag-containing nanoparticles in thin polymer films [J].

Fritzsche, W ;

Porwol, H ;

Wiegand, A ;

Bornmann, S ;

Kohler, JM .

NANOSTRUCTURED MATERIALS, 1998, 10 (01) :89-97

[3]

HACHE F, 1986, J OPT SOC AM B, V3, P790

[4] Fabrication, characterization and optical theory of aluminum nanometal nanoporous membrane thin film composites [J].

Hornyak, GL ;

Phani, KLN ;

Kunkel, DL ;

Menon, VP ;

Martin, CR .

NANOSTRUCTURED MATERIALS, 1995, 6 (5-8) :839-842

[5] OPTICAL CONSTANTS OF NOBLE METALS [J].

JOHNSON, PB ;

CHRISTY, RW .

PHYSICAL REVIEW B, 1972, 6 (12) :4370-4379

[6]

KINERI T, 1994, THESIS SCI U TOKYO N

[7]

Maxwell-Garnett J. C., 1906, PHILOS T ROY SOC LON, V205, P237, DOI DOI 10.1098/RSTA.1906.0007

[8] SURFACE-ENHANCED SPECTROSCOPY [J].

MOSKOVITS, M .

REVIEWS OF MODERN PHYSICS, 1985, 57 (03) :783-826

[9]

SANCHEZCORES S, 1995, J COLLOID INTERF SCI, V6, P358

[10] THE APPLICATION OF SIMULTANEOUS CHEMILUMINESCENCE AND THERMAL-ANALYSIS FOR STUDYING THE GLASS-TRANSITION AND OXIDATIVE STABILITY OF POLY(N-VINYL-2-PYRROLIDONE) [J].

SCHEIRS, J ;

BIGGER, SW ;

THEN, ETH ;

BILLINGHAM, NC .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1993, 31 (03) :287-297

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