A simple and efficient catalyst system for the asymmetric transfer hydrogenation of ketones

被引：24

作者：

Ahlford, Katrin ^{[1
]}

Zaitsev, Alexey B. ^{[1
]}

Ekstrm, Jesper ^{[1
]}

Adolfsson, Hans ^{[1
]}

机构：

[1] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

来源：

SYNLETT | 2007年 / 16期

关键词：

asymmetric catalysis; hydrogen transfer; reductions; rhodium; ketones;

D O I：

10.1055/s-2007-986653

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl alkyl ketones are efficiently and selectively reduced (up to 97% ee) under transfer-hydrogenation conditions in 2-propanot using rhodium catalysts based on readily available amino acid derived hydroxamic acid ligands.

引用

页码：2541 / 2544

页数：4

共 44 条

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