Functional polythiiranes 9: Stilbene mesogen side chain polythiirane

被引:4
作者
Bonnans-Plaisance, C [1 ]
Corvazier, L
Emery, J
Nicol, E
机构
[1] Univ Maine, UMR 6515, F-72085 Le Mans 9, France
[2] Univ Maine, UPRES A 6087, Lab Phys Etat Condense, F-72085 Le Mans, France
关键词
D O I
10.1007/s002890050397
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polythiirane containing pendant mesogenic stilbene units was synthesized by ring opening polymerization of the corresponding monomer. The synthetic convergent pathway used for the monomer synthesis involved several steps including a Wittig reaction in order to obtain the stilbene unit. The insoluble polymer was characterized by high resolution CP/MAS 13C NMR. The thermotropic liquid crystalline mesomorphism of the polymer was studied by conventional methods. A mechanical dynamical thermal analysis completes the polymer characterization.
引用
收藏
页码:525 / 532
页数:8
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