Electrolysis of water in a system with a solid polymer electrolyte at elevated pressure

被引：45

作者：

Grigor'ev, SA

Khaliullin, MM

Kuleshov, NV

Fateev, VN

机构：

[1] Russian Res Ctr Kurchatov Inst, Moscow 123182, Russia

[2] Moscow Power Engn Inst, Moscow 111250, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2001年 / 37卷 / 08期

关键词：

Polymer; Experimental Data; Physical Chemistry; Mathematical Model; Polymer Electrolyte;

D O I：

10.1023/A:1016735003101

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrolysis of water in a system with a solid polymer electrolyte (SPE) at pressures elevated up to 3.0 MPa is studied. A mechanism of the effect of elevated pressure on the electrolysis electrochemistry is proposed. A mathematical model and relevant software, which allow one to model current-voltage curves of an SPE-based electrolyzing cell on the basis of reference and experimental data, are designed.

引用

页码：819 / 822

页数：4

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[2]

Chizmadzhev Yu.A., 1971, Macro-Kinetics of Processes in Porous Media

[3]

Fateev V. N., 1993, ELEKTROKHIMIYA, V29, p[551, 551]

[4]

Gamburg Yu.D., 1997, ELEKTROKHIMICHESKAYA

[5]

KHALIOULLIN M, 1999, P HYP 3 INT S ST PET, P70

[6]

KOROVIN NV, 1967, ELEKTROKHIMIYA, V3, P635

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LU, PWT ;

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