Synthesis of methyl-substituted main-chain-type organoboron quinolate, polymers and their emission color tuning

被引：53

作者：

Nagata, Yuuya ^{[1
]}

Chujo, Yoshiki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

MACROMOLECULES | 2008年 / 41卷 / 08期

关键词：

D O I：

10.1021/ma7025918

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Highly fluorescent main-chain-type organoboron quinolate polymers were prepared by means of Sonogashira-Hagihara coupling reaction between diyne monomers and methyl-substituted diiodo-organoboron quinolates. By combining methyl substitution of quinolinol ligands and incorporation of organoboron quinolate into polymer main chain, more efficiently luminescent materials with blue-shifted emission were successfully synthesized.

引用

页码：2809 / 2813

页数：5

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