Protodesilylation of 2,6-disubstituted silyphosphinines.: Experimental and theoretical study

被引：15

作者：

Blug, Matthias ^{[1
]}

Piechaczyk, Olivier ^{[1
]}

Fustier, Marie ^{[1
]}

Mezailles, Nicolas ^{[1
]}

Le Floch, Pascal ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 08期

关键词：

D O I：

10.1021/jo800105b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,6-Disilylphosphinines react with HCl in ethereal solution to cleanly yield the corresponding 2,6-unsubstituted derivatives. DFT calculations allowed rationalization of the mechanism of this protodesilylation.

引用

页码：3258 / 3261

页数：4

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