How Many Lithium Ions Can Be Inserted onto Fused C6 Aromatic Ring Systems?

被引：286

作者：

Han, Xiaoyan ^{[1
]}

Qing, Guangyan ^{[1
]}

Sun, Jutang ^{[2
]}

Sun, Taolei ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 21期

基金：

美国国家科学基金会;

关键词：

aromaticity; carbon-based materials; ion-molecule reactions; lithium; organic electrodes; LI-ION; ENERGY-STORAGE; BATTERIES; CARBON; PERFORMANCE; CHALLENGES; ELECTRODES; POLYMERS; SURFACE; ANODES;

D O I：

10.1002/anie.201109187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Getting a charge out of lithium: The naphthalene derivative NTCDA is used to demonstrate a novel lithium ion insertion model in which each ring carbon atom can reversibly accept a lithium ion, giving discharge capacities of up to nearly 2000 mAhg -1. This method provides a new strategy for the design of high-performance organic electrodes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5147 / 5151

页数：5

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