(N-Heterocyclic carbene) Gold(I)-Catalyzed cycloisomerization of cyclohexadienyl Alkynes to Tetracyclo[3.3.0.02,8.04,6] octanes

被引：77

作者：

Kim, Soo Min ^{[1
]}

Park, Ji Hoon ^{[1
]}

Choi, Soo Young ^{[1
]}

Chung, Young Keun ^{[1
]}

机构：

[1] Coll Nat Sci, Intelligent Text Syst Res Ctr, Dept Chem, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 32期

关键词：

cycloisomerization; enynes; gold; strained ringcompounds;

D O I：

10.1002/anie.200702028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Biscyclopropanation: Dienynes containing a cyclohexadienyl unit can be converted into tetracyclo[3.3.0.0 2,8.04,6]-octanes by treatment with an (N-heterocyclic carbene)gold catalyst. When the dienynes bear an open-chain diene instead of cyclohexadiene, open-cage compounds, with two sides missing from the cage, are obtained. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6172 / 6175

页数：4

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