A mean-field theory of wetting by ionic solutions

被引：6

作者：

Denesyuk, NA ^{[1
]}

Hansen, JP ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

EUROPHYSICS LETTERS | 2003年 / 63卷 / 02期

关键词：

D O I：

10.1209/epl/i2003-00524-7

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The problem of wetting of a solid substrate by an ionic solution is examined theoretically, combining the classic Cahn theory for the solvent with the non-linear Poisson-Boltzmann treatment of the solute. The nature and location of the corresponding wetting transition are found to be particularly sensitive to the range and strength of the electrostatic interactions. These can be tuned, respectively, by changing the salt concentration and the substrate surface charge.

引用

页码：261 / 267

页数：7

共 14 条

[1]

[Anonymous], 1988, PHASE TRANSITIONS CR

[2] Scaling for mixtures of hard ions and dipoles in the mean spherical approximation [J].

Blum, L .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (02) :756-765

[3] Wetting transitions [J].

Bonn, D ;

Ross, D .

REPORTS ON PROGRESS IN PHYSICS, 2001, 64 (09) :1085-1163

[4] CRITICAL-POINT WETTING [J].

CAHN, JW .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (08) :3667-3672

[5] STRUCTURAL COMPONENT OF DISJOINING PRESSURE [J].

DERJAGUIN, BV ;

CHURAEV, NV .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1974, 49 (02) :249-255

[6] ANALYTIC RESULTS FOR WETTING TRANSITIONS IN THE PRESENCE OF VANDERWAALS TAILS [J].

DIETRICH, S ;

NAPIORKOWSKI, M .

PHYSICAL REVIEW A, 1991, 43 (04) :1861-1885

[7] Density functional theory of long-range critical wetting [J].

González, A ;

da Gama, MMT .

PHYSICAL REVIEW E, 2000, 62 (05) :6571-6576

[8] EFFECT OF SURFACE-IONIZATION ON WETTING LAYERS [J].

KAYSER, RF .

PHYSICAL REVIEW LETTERS, 1986, 56 (17) :1831-1834

[9] Repulsive forces between charged surfaces in water, and the cause of the Jones-Ray effect [J].

Langmuir, I .

SCIENCE, 1938, 88 :430-432

[10] SURFACE FORCES IN ADSORBED MULTILAYERS OF WATER ON QUARTZ [J].

PASHLEY, RM ;

KITCHENER, JA .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1979, 71 (03) :491-500

← 1 2 →