Properties of photoexcited states of C180, a triangle trimer of C60

被引:8
作者
Fujitsuka, M
Fujiwara, K
Murata, Y
Uemura, S
Kunitake, M
Ito, O
Komatsu, K
机构
[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Kyoto Univ, Chem Res Inst, Kyoto 6110011, Japan
[3] Kumamoto Univ, Kumamoto 8608555, Japan
关键词
D O I
10.1246/cl.2001.384
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photophysical properties of C-180 "cis-2/cis-2/cis-2", a triangle triad of C-60, were investigated by various methods including a transient absorption spectroscopy. Fluorescence and triplet absorption spectra were similar to those of C-120 (C-60 dimer) and other 1,2-adducts of C-60. On the other hand, short fluorescence lifetime and small quantum yield for the intersystem crossing process indicate that the photophysical properties of C-180 are affected by the non-radiative process in the singlet excited state.
引用
收藏
页码:384 / 385
页数:2
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