A topology paradigm for metal-organic zeolites

被引:103
作者
Rusanov, EB
Ponomarova, VV
Komarchuk, VV
Stoeckli-Evans, H
Fernandez-Ibañez, E
Stoeckli, F
Sieler, J
Domasevitch, KV
机构
[1] Natl Taras Shevchenko Univ Kiev, Dept Inorgan Chem, UA-01033 Kiev, Ukraine
[2] Inst Organ Chem, UA-02094 Kiev, Ukraine
[3] Univ Neuchatel, Dept Chem, CH-2007 Neuchatel, Switzerland
[4] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
关键词
crystal engineering; inclusion compounds; microporous materials; self-assembly; zeolites;
D O I
10.1002/anie.200250534
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Unprecedented coordination polymers of hexagonal tungsten bronze topology represent a new type of metal-organic zeolites: the compounds have a microporous structure, they are thermally stable and are capable of the reversible adsorption of dichloromethane (see picture).
引用
收藏
页码:2499 / 2501
页数:3
相关论文
共 42 条
[1]  
[Anonymous], 1995, ARNOLD LOND
[2]  
Bansal R.C., 1988, Active Carbon, P119
[3]   Construction of extended networks with a trimeric pyrazole synthon [J].
Boldog, I ;
Rusanov, EB ;
Sieler, J ;
Blaurock, S ;
Domasevitch, KV .
CHEMICAL COMMUNICATIONS, 2003, (06) :740-741
[4]  
Boldog I, 2001, ANGEW CHEM INT EDIT, V40, P3435, DOI 10.1002/1521-3773(20010917)40:18<3435::AID-ANIE3435>3.0.CO
[5]  
2-M
[6]   Coordination polymers of CoII and 3,3′,5,5′-tetramethyl-4,4′-bipyrazolyl:: a novel metal-organic three-dimensional network with four-coordinated planar vertices [J].
Boldog, I ;
Rusanov, EB ;
Chernega, AN ;
Sieler, J ;
Domasevitch, KV .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (06) :893-897
[7]  
Boldog I., 2001, ANGEW CHEM, V113, P3543
[8]  
DUBININ MM, 1975, PROG SURF MEMBR SCI, V19, P1
[9]   Highly porous and stable metal-organic frameworks: Structure design and sorption properties [J].
Eddaoudi, M ;
Li, HL ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1391-1397
[10]   Geometric requirements and examples of important structures in the assembly of square building blocks [J].
Eddaoudi, M ;
Kim, J ;
Vodak, D ;
Sudik, A ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4900-4904